Benchmarking the performance of all-solid-state lithium batteries

S Randau, DA Weber, O Kötz, R Koerver, P Braun… - Nature Energy, 2020 - nature.com
S Randau, DA Weber, O Kötz, R Koerver, P Braun, A Weber, E Ivers-Tiffée, T Adermann…
Nature Energy, 2020nature.com
Increasing the specific energy, energy density, specific power, energy efficiency and energy
retention of electrochemical storage devices are major incentives for the development of all-
solid-state batteries. However, a general evaluation of all-solid-state battery performance is
often difficult to derive from published reports, mostly due to the interdependence of
performance measures, but also due to the lack of a basic reference system. Here, we
present all-solid-state batteries reduced to the bare minimum of compounds, containing only …
Abstract
Increasing the specific energy, energy density, specific power, energy efficiency and energy retention of electrochemical storage devices are major incentives for the development of all-solid-state batteries. However, a general evaluation of all-solid-state battery performance is often difficult to derive from published reports, mostly due to the interdependence of performance measures, but also due to the lack of a basic reference system. Here, we present all-solid-state batteries reduced to the bare minimum of compounds, containing only a lithium metal anode, β-Li3PS4 solid electrolyte and Li(Ni0.6Co0.2Mn0.2)O2 cathode active material. We use this minimalistic system to benchmark the performance of all-solid-state batteries. In a Ragone-type graph, we compare literature data for thiophosphate-, oxide-, phosphate- and polymer-based all-solid-state batteries with our minimalistic cell. Using fundamental equations for key performance parameters, we identify research targets towards high energy, high power and practical all-solid-state batteries.
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