The increasing demand for ubiquitous wireless connectivity has led to the widespread of Wi-Fi networks. However, due to the limited coverage of Wi-Fi networks, mobile stations (STAs) need to frequently search for neighboring Wi-Fi access points (APs). Inevitable inefficiency occurs during the Wi-Fi scanning since the STA typically does not have any prior knowledge of the neighboring APs, thus leading to unnecessary waste of time and energy. In this paper, we propose BlueScan, a scheme to boost Wi-Fi scanning using collocated Bluetooth radio. BlueScan enhances Wi-Fi scanning with low power Bluetooth radio by identifying the operating channels and target beacon transmission times (TBTTs) of neighboring APs, thus changing the Wi-Fi scanning from a blind search to an intelligent search. We implement a prototype of BlueScan using Ubertooth platform, and evaluate its performance through real experiments. Our results demonstrate that BlueScan reduces the scanning delay up to 77% compared to legacy Wi-Fi scanning.