Heat and mass transport are obtained in a solar reactor using ‘in situ’ measurements linked to numerical simulation and allow the interpretation of the vaporization process as well as the determination of the cooling regime. Comparison with other processes (laser ablation or electric arc) point out some common behavior like the great influence of the cooling rate of vapors on the structure and yield of nanostructured carbon material. We also investigate the growth mechanisms of single wall carbon nanotubes (SWNTs) produced by the solar method as a function of the nature of catalysts and the temperature variation in the condensing area. The Raman spectra clearly show that the change of catalyst induces differences in the diameter of SWNT whereas TEM pictures enhance the change of both length and diameter of the bundles. All these results are explained considering that the key parameter is the temperature at which the SWNTs are formed. This temperature range can be related to the sublimation temperature of the target and to the eutectic temperature of the binary phase diagram. Finally we propose a new mechanism to explain the nucleation process and segregation rate which seems to depend on the capacity of catalyst to form carbide.