Cationic terminal borylene complexes: Interconversion of amino and alkoxy borylenes by an unprecedented Meerwein-Ponndorf hydride transfer.
Angewandte Chemie (International ed. in English), 2006•ora.ox.ac.uk
(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with
benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to
the coordinated ketone generates 2 (see structure), the first example of an imine-donor-
stabilized borylene complex, and the first cationic alkoxyborylene system.© 2006 Wiley-VCH
Verlag GmbH and Co. KGaA.
benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to
the coordinated ketone generates 2 (see structure), the first example of an imine-donor-
stabilized borylene complex, and the first cationic alkoxyborylene system.© 2006 Wiley-VCH
Verlag GmbH and Co. KGaA.
(Chemical Equation Presented) It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein-Ponndorf β-hydride transfer from the aminoborylene ligand to the coordinated ketone generates 2 (see structure), the first example of an imine-donor-stabilized borylene complex, and the first cationic alkoxyborylene system. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
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