Water-soluble organic aerosol (WSOA) in fine particles (PM_2.5) collected during wintertime in a polluted city (Handan) in Northern China was characterized using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (AMS). Through comparing with real-time measurements from a collocated Aerosol Chemical Speciation Monitor (ACSM), we determined that WSOA on average accounts for 29% of total organic aerosol (OA) mass and correlates tightly with secondary organic aerosol (SOA; Pearson's r = 0.95). The mass spectra of WSOA closely resemble those of ambient SOA, but also show obvious influences from coal combustion and biomass burning. Positive matrix factorization (PMF) analysis of the WSOA mass spectra resolved a water-soluble coal combustion OA (WS-CCOA; O/C = 0.17), a water-soluble biomass burning OA (WS-BBOA; O/C = 0.32), and a water-soluble oxygenated OA (WS-OOA; O/C = 0.89), which account for 10.3%, 29.3% and 60.4% of the total WSOA mass, respectively. The water-solubility of the OA factors was estimated by comparing the offline AMS analysis results with the ambient ACSM measurements. OOA has the highest water-solubility of 49%, consistent with increased hygroscopicity of oxidized organics induced by atmospheric aging processes. In contrast, CCOA is the least water soluble, containing 17% WS-CCOA. The distinct characteristics of WSOA from different sources extend our knowledge of the complex aerosol chemistry in the polluted atmosphere of Northern China and the water-solubility analysis may help us to understand better aerosol hygroscopicity and its effects on radiative forcing in this region.