This research investigates the quantity of municipal solid waste produced during the dry season, and its characterization at Eyenkorin dumpsite of Ilorin metropolis, along the Lagos-Ilorin express way. The physicochemical and thermal compositions of the combustible fractions of municipal solid waste were analysed, to ascertain the available calorific value. In this research, the quantity (tonnes) of waste generated, the rate of generation (kg per capita per day), its sustainability and the likely energy and power potentials in the dry season, were essentially predicted. The population responsible for municipal solid waste generation during this study was 1,120,834 people. During the characterization study from November 2018 to February 2019, it was established that 203,831 tonnes of municipal solid waste was produced during the four months of the dry season, at the rate of 1.12 kg per capita per day. It was found that 280 tonnes/day of municipal solid waste with low heating value of 19 MJ kg^-1, would generate 1478 MWh of heat energy and 18 MW of electrical energy potentials discretely, and grid of 13 kW.