Chasing Aqueous Biphasic Systems from Simple Salts by Exploring the LiTFSI/LiCl/H2O Phase Diagram

N Dubouis, C Park, M Deschamps… - ACS central …, 2019 - ACS Publications
phase separation to occur, ie, in the aqueous case, for an ABS to form. Here we show that
even mixtures of two monovalent salts sharing a common simple … two aqueous liquid phases

Chasing Aqueous Biphasic Systems from Simple Salts by Exploring the LiTFSI

N Dubouis, C Park, M Deschamps… - 2018 - chemrxiv.org
… The phase diagram of ternary LiTFSI / LiCl / H2O mixtures reveals the possibility to form
Aqueous Biphasic Systems with simple monovalent salts with a common cation. …

Understanding the role of electrolytes solvation structure for electrochemical energy storage applications

N Dubouis - 2021 - theses.hal.science
… The formation of aqueous biphasic systems is assessed for different lithium salts, and the
physics that drives the formation of such intriguing systems is explored thanks to the analysis of …

Direct imaging of micrometer-thick interfaces in saltsalt aqueous biphasic systems

D Degoulange, R Pandya… - Proceedings of the …, 2023 - National Acad Sciences
Studying the LiCl–LiTFSI–water and the HCl–LiTFSI–water … relates to how the nature
of the cations influences temperature dependence of the phase diagram for saltsalt ABSs. …

Anion specific effects drive the formation of Li-salt based aqueous biphasic systems

N Dubouis, A France-Lanord, A Brige… - The Journal of …, 2021 - ACS Publications
phase separations could be observed at large salt concentrations. Thus, the phase diagrams
for the various LiX–LiTFSI–H 2 O systems … Interestingly, when the different phase diagrams

Structure, dynamics and phase behavior of concentrated electrolytes for applications in energy storage devices

C Park - 2021 - edoc.hu-berlin.de
… the electrochemical measurements and realized the phase diagram. A. Grimaud and N. …
Their composition usually involves a concentrated inorganic salt and an ionic liquid. We explore

Two-Steps Halogen Intercalation Mechanism in Dual-Ion Batteries Enabled by Aqueous Biphasic Systems

D Degoulange, G Rousse, A Grimaud - 2023 - chemrxiv.org
… lithium halide salts such as LiCl or LiBr, aqueous biphasic systems (ABS) were … Chasing
Aqueous Biphasic Systems from Simple Salts by Exploring the LiTFSI/LiCl/H2O Phase Diagram

Two-Step Mechanism for Halogen Intercalation in Graphite Enabled by Aqueous Biphasic Systems

D Degoulange, G Rousse, A Grimaud - ACS Energy Letters, 2023 - ACS Publications
… Hence our results show that a higher salt concentration favors the oxidation of halides to …
TFSI-rich phase. To confirm this assertion, the phase diagram for the LiBr 3 –LiTFSI system was …

Revisiting the driving force inducing phase separation in PEG–phosphate aqueous biphasic systems

S Bonnassieux, R Pandya, DA Skiba… - Faraday …, 2024 - pubs.rsc.org
Studying saltsalt ABSs sharing common cations (Li + ), we have recently highlighted the …
Prior to characterizing the polymer–salt system, we first study the phase diagrams of two …

Fate of metal ions in PEG-400/Na2SO4/H2O aqueous biphasic system: From eviction to extraction towards the upper polymer-rich phase

E Sinoimeri, AC Pescheux, I Guillotte, J Cognard… - Separation and …, 2023 - Elsevier
salts were added as solutes in an aqueous solution of the phosphate buffer while in our
protocol, metal salts have been added in an aqueous … samples in the phase diagram are almost …