Chiral Recognition of Carboxylate Anions by (R)-BINOL-Based Macrocyclic Receptors
A Tyszka-Gumkowska, G Pikus, J Jurczak - Molecules, 2019 - mdpi.com
A Tyszka-Gumkowska, G Pikus, J Jurczak
Molecules, 2019•mdpi.comThree (R)-BINOL-based macrocyclic receptors obtained via double-amidation reaction were
used for chiral recognition of four anions derived from α-hydroxy and α-amino acids. The
structural factors of hosts and guests that affect chiral recognition processes were also
investigated, indicating that the proper geometry of both receptor and guest molecules plays
a crucial role in effective enantio-discrimination.
used for chiral recognition of four anions derived from α-hydroxy and α-amino acids. The
structural factors of hosts and guests that affect chiral recognition processes were also
investigated, indicating that the proper geometry of both receptor and guest molecules plays
a crucial role in effective enantio-discrimination.
Three (R)-BINOL-based macrocyclic receptors obtained via double-amidation reaction were used for chiral recognition of four anions derived from α-hydroxy and α-amino acids. The structural factors of hosts and guests that affect chiral recognition processes were also investigated, indicating that the proper geometry of both receptor and guest molecules plays a crucial role in effective enantio-discrimination.
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