The blending technique used in internal combustion engines can reduce emission of toxic exhaust components and noises, enhance overall energy efficiency and reduce fuel costs. The aim of the study was to compare the effects of dual alcohols (methanol and ethanol) blended in gasoline fuel (GF) against performance, combustion and emission characteristics. Problems arise in the fuel delivery system when using the highly volatile methanol-gasoline blends. This problem is reduced by using special fuel manifold. However, the satisfactory engine performance of the dual alcohol–gasoline blends need to be proved. The test fuels were GF, blend M35g65 (35% methanol, and 65% GF by volume), blend E40g60 (40% ethanol, and 6o% GF by volume). The blend M35g65 was selected to match the vapor pressure (VP) of GF. The test fuels were a lean mixture with excess-air ratio of λ= 1.1. The reaction parameters are taken from literatures and fitting calculations. Mathematical model and Computer software AVL program were conducted on a naturally-aspirated, spark ignition engine. The results show that indicate thermal efficiency (ITE) improved whereas the exhaust gas temperature (EGT) of the blends reduced, which is a benefit that reduces compression work. The regulated emissions were also reported. The blend E40g60 was recommended in preference to use because the former had shortened combustion duration, high energy content and its VP was selectively matched to that of GF's.