[HTML][HTML] Communication: Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural …
T Hecksher, B Jakobsen - The Journal of chemical physics, 2014 - pubs.aip.org
A recent study [C. Gainaru, R. Figuli, T. Hecksher, B. Jakobsen, JC Dyre, M. Wilhelm, and R.
Böhmer, Phys. Rev. Lett. 112, 098301 (2014)] of two supercooled monohydroxy alcohols
close to the glass-transition temperature showed that the Debye peak, thus far mainly
observed in the electrical response, also has a mechanical signature. In this work, we apply
broadband shear-mechanical spectroscopy to a systematic series of octanol structural
isomers, x-methyl-3-heptanol (with x ranging from 2 to 6). We find that the characteristics of …
Böhmer, Phys. Rev. Lett. 112, 098301 (2014)] of two supercooled monohydroxy alcohols
close to the glass-transition temperature showed that the Debye peak, thus far mainly
observed in the electrical response, also has a mechanical signature. In this work, we apply
broadband shear-mechanical spectroscopy to a systematic series of octanol structural
isomers, x-methyl-3-heptanol (with x ranging from 2 to 6). We find that the characteristics of …
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