Contemporary carbocation chemistry: applications in organic synthesis

RR Naredla, DA Klumpp - Chemical reviews, 2013 - ACS Publications
Chemical reviews, 2013ACS Publications
… The diverse chemistry of carbocations has also received considerable attention from the
academic community, with carbocation-based synthetic reactions being used in
methodology development and targeted organic synthesis. Despite the long history of
synthetic carbocation chemistry, this continues to be an area of intensive research. As
described in the following review, new methodologies are being developed for C–C bond
construction, functional group manipulation, activation of sp 3 carbons, and rearrangements …
The extraordinary instability of such an ‘ion’accounts for many of the peculiarities of organic reactions. Frank C. Whitmore, 1932
ACS Publications
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