Controlled aqueous polymerization of acrylamides and acrylates and “in situ” depolymerization in the presence of dissolved CO 2
DJ Lloyd, V Nikolaou, J Collins, C Waldron… - Chemical …, 2016 - pubs.rsc.org
Chemical Communications, 2016•pubs.rsc.org
Aqueous copper-mediated radical polymerization of acrylamides and acrylates in
carbonated water resulted in high monomer conversions (t< 10 min) before undergoing
depolymerization (60 min> t> 10 min). The regenerated monomer was characterized and
repolymerized following deoxygenation of the resulting solutions to reyield polymers in high
conversions that exhibit low dispersities.
carbonated water resulted in high monomer conversions (t< 10 min) before undergoing
depolymerization (60 min> t> 10 min). The regenerated monomer was characterized and
repolymerized following deoxygenation of the resulting solutions to reyield polymers in high
conversions that exhibit low dispersities.
Aqueous copper-mediated radical polymerization of acrylamides and acrylates in carbonated water resulted in high monomer conversions (t < 10 min) before undergoing depolymerization (60 min > t > 10 min). The regenerated monomer was characterized and repolymerized following deoxygenation of the resulting solutions to reyield polymers in high conversions that exhibit low dispersities.
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