Controlling the nonadiabatic electron-transfer reaction rate through molecular-vibration polaritons in the ultrastrong coupling regime
Recent experiments showed that the chemical reaction rate is modified, either increased or
decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical
cavity. Herein we investigate how the rate of an electron-transfer reaction depends on the
molecule-cavity coupling in the ultrastrong coupling regime, where the coupling strength is
comparable in magnitude with both the vibrational and the cavity frequencies. We found two
main factors that determine the modification of the reaction rate: the relative shifts of the …
decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical
cavity. Herein we investigate how the rate of an electron-transfer reaction depends on the
molecule-cavity coupling in the ultrastrong coupling regime, where the coupling strength is
comparable in magnitude with both the vibrational and the cavity frequencies. We found two
main factors that determine the modification of the reaction rate: the relative shifts of the …
Controlling the nonadiabatic electron-transfer reaction rate through molecular-vibration polaritons in the ultrastrong coupling regime
Recent experiments showed that the chemical reaction rate is modified, either increased or
decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical
cavity. Herein we investigate how the rate of an electron-transfer reaction depends on the
molecule-cavity coupling in the ultrastrong coupling regime, where the coupling strength is
comparable in magnitude with both the vibrational and the cavity frequencies. We found two
main factors that determine the modification of the reaction rate: the relative shifts of the …
decreased, by strongly coupling a nuclear vibration mode to the single mode of an optical
cavity. Herein we investigate how the rate of an electron-transfer reaction depends on the
molecule-cavity coupling in the ultrastrong coupling regime, where the coupling strength is
comparable in magnitude with both the vibrational and the cavity frequencies. We found two
main factors that determine the modification of the reaction rate: the relative shifts of the …
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