Controlling the secondary structure of nonbiological oligomers with solvophobic and coordination interactions

RB Prince, T Okada, JS Moore - … Chemie International Edition, 1999 - Wiley Online Library
Angewandte Chemie International Edition, 1999Wiley Online Library
Making use of a combination of metal–ligand coordination interactions and solvophobic
forces, an oligomer based on phenylacetylene incorporates Ag+ ions to form a highly
ordered helical structure. The space‐filling model shown makes clear the trigonal‐planar
coordination environment at silver.
Abstract
Making use of a combination of metal–ligand coordination interactions and solvophobic forces, an oligomer based on phenylacetylene incorporates Ag+ ions to form a highly ordered helical structure. The space‐filling model shown makes clear the trigonal‐planar coordination environment at silver.
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