Copper‐Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3‐Containing Alkyl Azides
F Wang, X Qi, Z Liang, P Chen, G Liu - Angewandte Chemie, 2014 - Wiley Online Library
F Wang, X Qi, Z Liang, P Chen, G Liu
Angewandte Chemie, 2014•Wiley Online LibraryA novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been
developed under mild reaction conditions. A variety of CF3‐containing organoazides were
directly synthesized from a wide range of olefins, including activated and unactivated
alkenes, and the resulting products can be easily transformed into the corresponding CF3‐
containing amine derivatives.
developed under mild reaction conditions. A variety of CF3‐containing organoazides were
directly synthesized from a wide range of olefins, including activated and unactivated
alkenes, and the resulting products can be easily transformed into the corresponding CF3‐
containing amine derivatives.
Abstract
A novel copper‐catalyzed intermolecular trifluoromethylazidation of alkenes has been developed under mild reaction conditions. A variety of CF3‐containing organoazides were directly synthesized from a wide range of olefins, including activated and unactivated alkenes, and the resulting products can be easily transformed into the corresponding CF3‐containing amine derivatives.
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