Counteranion-dependent mechanochromism of a photoluminescent platinum (ii) complex with mixed terpyridine and thioglucose
N Kitani, N Kuwamura, T Tsukuda… - Chemical …, 2014 - pubs.rsc.org
N Kitani, N Kuwamura, T Tsukuda, N Yoshinari, T Konno
Chemical Communications, 2014•pubs.rsc.orgMechanical grinding of the ClO4− salt of [Pt (H4tg-S)(terpy)]+(H5tg= 1-thio-β-D-glucose,
terpy= 2, 2′: 6′, 2′′-terpyridine), newly prepared from [PtCl (terpy)]+ and H4tg−, caused
its emission band at 630 nm to shift to 667 nm, while such mechanochromism was not
observed for the PF6− salt that shows an emission band at 670 nm.
terpy= 2, 2′: 6′, 2′′-terpyridine), newly prepared from [PtCl (terpy)]+ and H4tg−, caused
its emission band at 630 nm to shift to 667 nm, while such mechanochromism was not
observed for the PF6− salt that shows an emission band at 670 nm.
Mechanical grinding of the ClO4− salt of [Pt(H4tg-S)(terpy)]+ (H5tg = 1-thio-β-D-glucose, terpy = 2,2′:6′,2′′-terpyridine), newly prepared from [PtCl(terpy)]+ and H4tg−, caused its emission band at 630 nm to shift to 667 nm, while such mechanochromism was not observed for the PF6− salt that shows an emission band at 670 nm.
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