Coupling of electrons to intermolecular phonons in molecular charge transfer dimers: A resonance Raman study
D Pedron, A Speghini, V Mulloni… - The Journal of chemical …, 1995 - pubs.aip.org
We report resonance Raman scattering (RRS) spectra and Raman excitation profiles (REP)
of a system containing π dimers of identical molecular radical ions measured with laser
excitation in resonance with the charge transfer (CT) transition. A Peierls–Hubbard (PH)
Hamiltonian has been used to model the investigated system and to calculate its optical and
RRS properties. Results are reported for two polyoxometallate salts of tetrathiafulvalene
(TTF), namely (TTF) 2 (W6O19) and (TTF) 2 (Mo6O19) whose structures contain almost …
of a system containing π dimers of identical molecular radical ions measured with laser
excitation in resonance with the charge transfer (CT) transition. A Peierls–Hubbard (PH)
Hamiltonian has been used to model the investigated system and to calculate its optical and
RRS properties. Results are reported for two polyoxometallate salts of tetrathiafulvalene
(TTF), namely (TTF) 2 (W6O19) and (TTF) 2 (Mo6O19) whose structures contain almost …
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