Cross-dehydrogenative coupling reactions between arenes (C–H) and carboxylic acids (O–H): a straightforward and environmentally benign access to O-aryl esters
RSC advances, 2019•pubs.rsc.org
Transition-metal catalyzed cross-dehydrogenative-coupling reactions encompass highly
versatile and atom economical methods for the construction of various carbon–carbon and
carbon–heteroatom bonds by combining two C (X)–H (X= heteroatom) bonds. Along this
line, direct acyloxylation of C–H bonds with carboxylic acids has emerged as a powerful and
green approach for the synthesis of structurally diverse esters. In this focus-review we will
describe recent progress in direct esterification of aromatic C–H bonds with special …
versatile and atom economical methods for the construction of various carbon–carbon and
carbon–heteroatom bonds by combining two C (X)–H (X= heteroatom) bonds. Along this
line, direct acyloxylation of C–H bonds with carboxylic acids has emerged as a powerful and
green approach for the synthesis of structurally diverse esters. In this focus-review we will
describe recent progress in direct esterification of aromatic C–H bonds with special …
Transition-metal catalyzed cross-dehydrogenative-coupling reactions encompass highly versatile and atom economical methods for the construction of various carbon–carbon and carbon–heteroatom bonds by combining two C(X)–H (X = heteroatom) bonds. Along this line, direct acyloxylation of C–H bonds with carboxylic acids has emerged as a powerful and green approach for the synthesis of structurally diverse esters. In this focus-review we will describe recent progress in direct esterification of aromatic C–H bonds with special emphasis on the mechanistic features of the reactions. Literature has been surveyed until the end of February 2019.
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