phosphate based glasses, emphasising microstructural characterisation. The following
topics are discussed: nucleation kinetics in silicate systems, comparisons with classical
theory, and new evidence in the early stages of crystallisation of Li2O· 2SiO2 glass for the
appearance of previously unreported metastable precursor phases, probably crystalline
polymorphs of lithium disilicate; the role of P2O5 as a nucleating agent in lithia—silica …