[PDF][PDF] Densely cross-linked polysiloxane nanogels

IB Meshkov, AA Kalinina, VV Kazakova… - Ineos Open, 2020 - researchgate.net
IB Meshkov, AA Kalinina, VV Kazakova, AI Demchenko
Ineos Open, 2020researchgate.net
Nanogels can be called the new old § objects of polymer chemistry. New because we have
formulated the criteria for the assignment of objects to this group within the
macromoleculeparticle concept and developed the methods for their directed and controlled
synthesis. Old because the application of these criteria to the earlier known systems allows
us to surely classify them as nanogels. It is shown that this classification per se provides
insight into the organization of their molecular structures and enables directed modification …
Abstract
Nanogels can be called the new old § objects of polymer chemistry. New because we have formulated the criteria for the assignment of objects to this group within the macromoleculeparticle concept and developed the methods for their directed and controlled synthesis. Old because the application of these criteria to the earlier known systems allows us to surely classify them as nanogels. It is shown that this classification per se provides insight into the organization of their molecular structures and enables directed modification. This means a transition from the empirical control of the properties to molecular design. The current review presents a brief historical overview of densely cross-linked nanogels and their main synthetic routes and highlights the principles and approaches to the control of their structures and molecular-mass characteristics, application scope, and prospects for further development.
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