Direct precipitation of uranium from loaded organic in a microreactor

N Sen, S Ekhande, P Thakur, KK Singh… - Separation Science …, 2019 - Taylor & Francis
N Sen, S Ekhande, P Thakur, KK Singh, S Mukhopadhyay, R Sirsam, N Patil, KT Shenoy
Separation Science and Technology, 2019Taylor & Francis
ABSTRACT A continuous process to obtain ammonium diurate directly from uranium-loaded
organic phase in a microbore tube is presented. The proposed process combines two
different steps: multistage stripping and precipitation in a microbore tube. The effects of
different operating conditions (residence time, O/A ratio, and flow velocity) on percent
uranium removal, production rate, and space–time–yield (STY) have been studied. Percent
uranium removal as high as 99.5% is attained within a residence time of 3 min for O/A ratio …
Abstract
A continuous process to obtain ammonium diurate directly from uranium-loaded organic phase in a microbore tube is presented. The proposed process combines two different steps: multistage stripping and precipitation in a microbore tube. The effects of different operating conditions (residence time, O/A ratio, and flow velocity) on percent uranium removal, production rate, and space–time–yield (STY) have been studied. Percent uranium removal as high as 99.5% is attained within a residence time of 3 min for O/A ratio of 4. Corresponding value of STY is 3000 kg/day-m3 while ensuring a uranium concentration below 50 ppm in lean organic phase. Numerical simulations are carried out to understand the two-phase flow pattern inside the microbore tube. The results of the simulations are used to substantiate and explain the observed experimental trends.
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