Divergent Oxidative Couplings between Indoles and 2, 3-Dihydroxybenzoic Acid Derivatives for the Biomimetic Synthesis of Voacalgine A and Bipleiophylline
N Denizot, D Lachkar, C Kouklovsky, E Poupon… - …, 2018 - thieme-connect.com
N Denizot, D Lachkar, C Kouklovsky, E Poupon, L Evanno, G Vincent
Synthesis, 2018•thieme-connect.comThe present feature article details our endeavors towards the synthesis of the highly intricate
bisindole alkaloid bipleiophylline and its biosynthetic precursor voacalgine A: from the
development of a divergent oxidative coupling between indole and dihydroxybenzoic acids,
to the exploration of the chemical space from natural products and culminating in the
biomimetic assembly of voacalgine A and bipleiophylline.
bisindole alkaloid bipleiophylline and its biosynthetic precursor voacalgine A: from the
development of a divergent oxidative coupling between indole and dihydroxybenzoic acids,
to the exploration of the chemical space from natural products and culminating in the
biomimetic assembly of voacalgine A and bipleiophylline.
The present feature article details our endeavors towards the synthesis of the highly intricate bisindole alkaloid bipleiophylline and its biosynthetic precursor voacalgine A: from the development of a divergent oxidative coupling between indole and dihydroxybenzoic acids, to the exploration of the chemical space from natural products and culminating in the biomimetic assembly of voacalgine A and bipleiophylline.
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