This study aimed to develop an edible multilayer coating by electrostatic layer‐by‐layer deposition (LbL) of chitosan‐pectin biopolymers to extend the shelf life of strawberries. A fixed concentration of chitosan (2% w/v) and varying pectin concentrations (0.25–1% w/v) in an LbL sequence were initially applied to coat on the low‐density polyethylene (LDPE) film. The successful assembly of these biopolymers in the LDPE film was confirmed by their zeta potential (chitosan, +43 mV and pectin, −36 to −42 mV) and Fourier transform infrared (FTIR) spectroscopy in the range of 1800–1600 cm^‐1 indicating the strong interactions between chitosan and pectin. Chitosan (2% w/v) and pectin (0.25% w/v) had the lowest water vapour permeability (WVP) of 1.86 ± 0.02 × 10⁻⁹ in gday^‐1 m^‐1 Pa^‐1 among all other formulations. The application of the coating on strawberries extended the shelf life (9 days) compared to the control (6 days) at room temperature (25 °C) while still retaining the colour, firmness and pH of strawberries. The results obtained illuminate the potential application of safer, ecofriendly and sustainable packaging materials in the food industry.