Effect of SiO2 and TiO2 addition on the exaggerated grain growth of BaTiO3

YS Yoo, H Kim, DY Kim - Journal of the European Ceramic society, 1997 - Elsevier
YS Yoo, H Kim, DY Kim
Journal of the European Ceramic society, 1997Elsevier
The exaggerated grain growth (sometimes referred to as secondary recrystallization) during
sintering of BaTiO3 was studied with two different liquidforming additive oxides, TiO2 and
SiO2. The liquid phase was distributed inhomogeneously by placing a small amount of TiO2
and SiO2, respectively, on top of the BaTiO3 powder compact. The exaggerated grain
growth was observed to occur more rapidly in the SiO2-containing specimen than in the
TiO2-containing specimen. Once the initial fine-grained structure was completely replaced …
The exaggerated grain growth (sometimes referred to as secondary recrystallization) during sintering of BaTiO3 was studied with two different liquidforming additive oxides, TiO2 and SiO2. The liquid phase was distributed inhomogeneously by placing a small amount of TiO2 and SiO2, respectively, on top of the BaTiO3 powder compact. The exaggerated grain growth was observed to occur more rapidly in the SiO2-containing specimen than in the TiO2-containing specimen. Once the initial fine-grained structure was completely replaced by the exaggeratedly grown grains, the TiO2-containing specimen exhibited practically no more micro structural evolution. For the SiO2-containing specimen, on the other hand, a few grains continued to grow without limit. The observed unusual growth has been explained in terms of twin-assisted growth mechanism.
Elsevier
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