[PDF][PDF] Effect of molar concentration variation on the crystallite size and energy band gap of CdS nanoparticles synthesized by wet chemical route

SD Birajdar, B Shinde, B Kadam… - Int J Adv Res Basic …, 2015 - researchgate.net
SD Birajdar, B Shinde, B Kadam, M Kshirsagar, N Sarnaik, KM Jadhav
Int J Adv Res Basic and Appl Sci, 2015researchgate.net
The samples of CdS semiconductor nanoparticles with varying molar concentration were
synthesized by wet chemical route at room temperature. Structural characterization of
synthesized CdS semiconductor nanoparticles were performed by X-ray diffraction pattern
(XRD) while optical characterization were examined by UV-Visible absorption spectroscopy.
XRD pattern showed the as synthesized CdS nanoparticles have cubic (zinc blend) structure
with average crystallite size 12.23–9.02 nm and lattice constant a= 5.829 Ǻ. UV-Visible …
Abstract
The samples of CdS semiconductor nanoparticles with varying molar concentration were synthesized by wet chemical route at room temperature. Structural characterization of synthesized CdS semiconductor nanoparticles were performed by X-ray diffraction pattern (XRD) while optical characterization were examined by UV-Visible absorption spectroscopy. XRD pattern showed the as synthesized CdS nanoparticles have cubic (zinc blend) structure with average crystallite size 12.23–9.02 nm and lattice constant a= 5.829 Ǻ. UV-Visible absorption spectrum showed the band gap energy of the CdS nanoparticles are found in the range of 2.55-2.63 eV. The increase in band gap with the decrease of crystallite size of the nanoparticles is due to quantum confinement effect.
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