Elastic flexibility tuning via interaction factor modulation in molecular crystals
Chemical Communications, 2018•pubs.rsc.org
We report the design of a series of nonhalogenated and halogenated molecular crystals with
specific structural features, which are essential for pronounced elasticity. These features
involve (a) isotropic weak and dispersive interactions, and (b) corrugated molecular packing
with interlocked structures. The effects of intermolecular interactions on the elastic properties
of the crystals are ascertained using nano-scale mechanical characterization methods.
specific structural features, which are essential for pronounced elasticity. These features
involve (a) isotropic weak and dispersive interactions, and (b) corrugated molecular packing
with interlocked structures. The effects of intermolecular interactions on the elastic properties
of the crystals are ascertained using nano-scale mechanical characterization methods.
We report the design of a series of nonhalogenated and halogenated molecular crystals with specific structural features, which are essential for pronounced elasticity. These features involve (a) isotropic weak and dispersive interactions, and (b) corrugated molecular packing with interlocked structures. The effects of intermolecular interactions on the elastic properties of the crystals are ascertained using nano-scale mechanical characterization methods.
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