Electrochemical generation of ammonia (NH₃) from nitrogen (N₂) using renewable electricity is a desirable alternative to current NH₃ production methods, which consume roughly 1 % of the world's total energy use. The use of catalysts to manipulate the required electron and proton transfer reactions with low energy input is also a chemical challenge that requires development of fundamental reaction pathways. This work presents an approach to the electrochemical reduction of N₂ into NH₃ using a coordination complex of aluminum(III), which facilitates NH₃ production at −1.16 V vs. SCE. Reactions performed under ¹⁵N₂ liberate ¹⁵NH₃. Electron paramagnetic resonance spectroscopic characterization of a reduced intermediate and investigations of product inhibition, which limit the reaction to sub‐stoichiometric, are also presented.