Electronic, conjugation, and confinement effects on structure, redox, and catalytic behavior of oxido-vanadium (IV) and-(V) chiral Schiff base complexes
M Mandal, V Nagaraju, GV Karunakar… - The Journal of …, 2015 - ACS Publications
Change in oxophilicity, redox, and catalytic behavior with the modification of ligand system
was observed for four oxido-vanadium Schiff base complexes. Mononuclear V (IV)
complexes were obtained with methyl-substituted Schiff base ligand and one having higher
conjugation. Electronic and conjugation effects reduce the oxophilicity of vanadium and led
to mononuclear (LVIV O, L= Schiff base ligand) species. However, μ-oxido bridged
dinuclear [O VVOL] 2 complexes were formed with Schiff base ligands without such …
was observed for four oxido-vanadium Schiff base complexes. Mononuclear V (IV)
complexes were obtained with methyl-substituted Schiff base ligand and one having higher
conjugation. Electronic and conjugation effects reduce the oxophilicity of vanadium and led
to mononuclear (LVIV O, L= Schiff base ligand) species. However, μ-oxido bridged
dinuclear [O VVOL] 2 complexes were formed with Schiff base ligands without such …
[引用][C] Electronic, Conjugation, and Confinement Effects on Structure, Redox, and Catalytic Behavior of Oxido-Vanadium (IV) and-(V) Chiral Schiff Base Complexes
M Moon, N Vemu, S Bipul, BB Jyoti - 2015
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