Electronic structure of BaLi. II. First observation of the Ba6,7Li spectrum: Analysis of the (2)2Π→X2Σ+ system

J D'Incan, C Effantin, A Bernard, G Fabre… - The Journal of …, 1994 - pubs.aip.org
The thermal emission at high temperature (1100° C) of BaLi has been analyzed
spectroscopically at high resolution with a Fourier transform spectrometer. Molecular
emission in the infrared region is observed and is ascribed to a transition from the (2) 2Π
state towards the ground state X 2Σ+ of BaLi. These states (among several others) have
been predicted from ab initio calculations [see part I, AR Allouche and M. Aubert‐Frécon, J.
Chem. Phys. 100, 938 (1994)]. Very good agreement is observed between theoretical …
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