Enantioselective Henry reaction catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand and Cu (II) ion

G Koz, D Astley, ST Astley - Turkish Journal of Chemistry, 2011 - journals.tubitak.gov.tr
G Koz, D Astley, ST Astley
Turkish Journal of Chemistry, 2011journals.tubitak.gov.tr
Mild and efficient enantioselective Henry reactions of nitromethane with various aldehydes
were catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand in the presence of
Cu (II) ions, affording the corresponding adducts in high yields (up to 96%) and
enantioselectivities (up to 92% ee).
Abstract
Mild and efficient enantioselective Henry reactions of nitromethane with various aldehydes were catalyzed by a novel L-(+)-aspartic acid-derived Schiff base ligand in the presence of Cu (II) ions, affording the corresponding adducts in high yields (up to 96%) and enantioselectivities (up to 92% ee).
journals.tubitak.gov.tr
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