Coal is a vital basic energy source for any economy in the world, and our country is no exception. Our coal resources are abundant, with high production and demand, not comparable to oil and natural gas. The coal supply chain plays an equally important role in economic production, but unfortunately, the current coal supply chain is not focused on greening while creating profits. Unfortunately, the current coal supply chain does not focus on green production and energy conservation and emission reduction while creating profits, which has caused irreversible harm and loss to resources and environment. This has caused irreversible damage and loss to resources and the environment. The green supplier selection for coal enterprises is affirmed as multiple attribute decision making (MADM). In such paper, motivated by the idea of cosine similarity measure (CSM), the CSMs are extended to DVNSs and four CSMs are created under DVNSs. Then, two weighted CSMs are built for MADM under DVNSs. Finally, a numerical example for Green supplier selection for coal enterprises is affirmed and some comparative algorithms are produced to affirm the built method.