Experimental and theoretical study of the reaction of the ethynyl radical with nitrous oxide, C 2 H+ N 2 O
VS Nguyen, RMI Elsamra, J Peeters, SA Carl… - Physical Chemistry …, 2012 - pubs.rsc.org
We investigated the rate constants and reaction mechanism of the gas phase reaction
between the ethynyl radical and nitrous oxide (C2H+ N2O) using both experimental
methods and electronic structure calculations. A pulsed-laser photolysis/chemiluminescence
technique was used to determine the absolute rate coefficient over the temperature range
570 K to 836 K. In this experimental temperature range, the measured temperature
dependence of the overall rate constants can be expressed as: k (T)(C2H+ N2O)= 2.93× 10 …
between the ethynyl radical and nitrous oxide (C2H+ N2O) using both experimental
methods and electronic structure calculations. A pulsed-laser photolysis/chemiluminescence
technique was used to determine the absolute rate coefficient over the temperature range
570 K to 836 K. In this experimental temperature range, the measured temperature
dependence of the overall rate constants can be expressed as: k (T)(C2H+ N2O)= 2.93× 10 …
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