An experimental assessment of an air pocket (AP), confined in a compressed air vessel (CAV), has been investigated under several different water hammer (WH) events to better define the use of protection devices or compressed air energy storage (CAES) systems. This research focuses on the size of an AP within an air vessel and tries to describe how it affects important parameters of the system, i.e., the pressure in the pipe, stored pressure, flow velocity, displaced volume of water and water level in the CAV. Results present a specific range of air pockets based on a dimensionless parameter extractable for other real systems.