The temperature quenching luminescence effect of optical materials used for fluorescence intensity ratio temperature sensing seriously hinders the realization of temperature sensing in the high temperature region. In recent years, some abnormal thermal enhancement up-conversion materials have attracted extensive attention due to their great potential to sense temperature in high temperature regions. At present, few up-conversion luminescence thermal enhancement materials have reported, and the exploration of thermal enhancement luminescence mechanism is not thorough enough. In this work, new up-conversion luminescence materials Sc₂W₃O₁₂: Yb³⁺, Er³⁺ were prepared, and the thermal enhancement effect was successfully regulated by changing the Yb³⁺ concentration. The integral emission intensity and intensity of 521 nm at 753 K of Sc_1.42W₃O₁₂: 0.54Yb³⁺, 0.04Er³⁺ can reach 74.5 and 104.9 times of that at room temperature, respectively. In addition, the thermal enhancement luminescence property of up-conversion materials Sc₂W₃O₁₂: Yb³⁺, Er³⁺ was confirmed to be derived from negative thermal expansion properties based on two reference experiments. Finally, the dual temperature sensing model was established to sense the temperature. The results show that the up-conversion thermal enhancement luminescence material is a potential temperature sensing material with high sensitivity, wide temperature sensing range, high resolution and good thermal fatigue resistance.