Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane
Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with
formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These
compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes.
Notably, the boron is capable of acting as a shuttle for hydride transfer to substrates. The
results are interesting in the context of heterolytic substrate addition across metal–boron
bonds in metallaboratranes and related systems, as well as metal–ligand bifunctional …
formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These
compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes.
Notably, the boron is capable of acting as a shuttle for hydride transfer to substrates. The
results are interesting in the context of heterolytic substrate addition across metal–boron
bonds in metallaboratranes and related systems, as well as metal–ligand bifunctional …
Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes. Notably, the boron is capable of acting as a shuttle for hydride transfer to substrates. The results are interesting in the context of heterolytic substrate addition across metal–boron bonds in metallaboratranes and related systems, as well as metal–ligand bifunctional catalysis.
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