Homogeneous ruthenium-based water–gas shift catalysts via supported ionic liquid phase (SILP) technology at low temperature and ambient pressure
S Werner, N Szesni, RW Fischer, M Haumann… - Physical Chemistry …, 2009 - pubs.rsc.org
S Werner, N Szesni, RW Fischer, M Haumann, P Wasserscheid
Physical Chemistry Chemical Physics, 2009•pubs.rsc.org… Our group and others have recently introduced the so-called “supported ionic liquid
phase” (SILP) technology. In SILP … In conclusion, these results exemplify in a particularly
promising manner the advantages of supported ionic liquid phase catalysis. The
combination of homogeneous dissolved RuCl 3 , extremely low-volatile ionic liquid [BMMIM][OTf]
and porous silica support leads to a catalytic material that promotes the WGS reaction under
ambient pressure and at low temperatures. Clearly, the activity as well as the lifetime of such …
phase” (SILP) technology. In SILP … In conclusion, these results exemplify in a particularly
promising manner the advantages of supported ionic liquid phase catalysis. The
combination of homogeneous dissolved RuCl 3 , extremely low-volatile ionic liquid [BMMIM][OTf]
and porous silica support leads to a catalytic material that promotes the WGS reaction under
ambient pressure and at low temperatures. Clearly, the activity as well as the lifetime of such …
Novel ruthenium-based supported ionic liquid phase (SILP) catalysts for the water–gas shift (WGS) reaction are reported which, compared to classical low temperature shift systems, operate at much lower temperatures and even at ambient pressure.
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