Hydrolytic polycondensation of diethoxydimethylsilane in carbonic acid

AA Kalinina, IV Elmanovich, MN Temnikov… - RSC …, 2014 - pubs.rsc.org
AA Kalinina, IV Elmanovich, MN Temnikov, MA Pigaleva, AS Zhiltsov, MO Gallyamov
RSC advances, 2014pubs.rsc.org
A new process for producing silicones based on chlorine-free reagents is suggested.
Carbonic acid at elevated pressure and temperature is shown to be an effective reagent for
converting alkoxysilane to silicones. The process conditions make it possible to control the
ratio between linear and cyclic products.
A new process for producing silicones based on chlorine-free reagents is suggested. Carbonic acid at elevated pressure and temperature is shown to be an effective reagent for converting alkoxysilane to silicones. The process conditions make it possible to control the ratio between linear and cyclic products.
The Royal Society of Chemistry
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