Immobilized copper (II) complexes on montmorillonite and MCM-41 as selective catalysts for epoxidation of alkenes
Journal of Molecular Catalysis A: Chemical, 2005•Elsevier
Copper (II) complexes with 2, 2′-bipyridine (bpy) and 1, 8-dibenzyl-1, 3, 6, 8, 10, 13-
hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of
montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of
norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100%
selectivity toward the formation of the corresponding epoxides.
hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of
montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of
norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100%
selectivity toward the formation of the corresponding epoxides.
Copper(II) complexes with 2,2′-bipyridine(bpy) and 1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane (macrocycle) immobilized between silicate layers of montmorillonite and nanoreactors of MCM-41 successfully catalyze the epoxidation of norbornene and trans-2-hexene-1-ol with good to excellent reactivity and 48–100% selectivity toward the formation of the corresponding epoxides.
Elsevier
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