YVO₄:Bi³⁺,Eu³⁺ nanophosphor synthesized by the citrate route shows the photobleaching behavior, i.e., the decrease in photoluminescence intensity under the continuous irradiation of excitation light. This photobleaching property is remarkably suppressed by the washing post-treatment combined with centrifugation and the hydrothermal post-treatment. A relation between the fraction of photobleach and the amount of citrate ions coordinating to metallic ions at the surface of nanoparticles verifies that the photobleaching behavior of YVO₄:Bi³⁺,Eu³⁺ nanophosphor originates from the redox reaction between the citrate ions and V⁵⁺ in YVO₄ host crystal. The long-term light fastness test reveals that the hydrothermally treated YVO₄:Bi³⁺,Eu³⁺ nanophosphor has sufficient photostability for practical use over 15years outside.