In Situ Identification of Intermediates of Benzyl Chloride Reduction at a Silver Electrode by SERS Coupled with DFT Calculations
A Wang, YF Huang, UK Sur, DY Wu… - Journal of the …, 2010 - ACS Publications
Journal of the American Chemical Society, 2010•ACS Publications
Aiming to deeply understand the electrocatalytic mechanism of silver on reduction of benzyl
chloride, we carried out an in situ electrochemical surface-enhanced Raman spectroscopic
study to characterize various surface species in different electrode potential regions. A
further analysis with DFT calculation reveals that the benzyl radical and its anionic derivate
bonded on a silver electrode are the key intermediates, implying that the pathway could
drastically differ from the outer sphere concerted electron reduction at inert electrodes.
chloride, we carried out an in situ electrochemical surface-enhanced Raman spectroscopic
study to characterize various surface species in different electrode potential regions. A
further analysis with DFT calculation reveals that the benzyl radical and its anionic derivate
bonded on a silver electrode are the key intermediates, implying that the pathway could
drastically differ from the outer sphere concerted electron reduction at inert electrodes.
Aiming to deeply understand the electrocatalytic mechanism of silver on reduction of benzyl chloride, we carried out an in situ electrochemical surface-enhanced Raman spectroscopic study to characterize various surface species in different electrode potential regions. A further analysis with DFT calculation reveals that the benzyl radical and its anionic derivate bonded on a silver electrode are the key intermediates, implying that the pathway could drastically differ from the outer sphere concerted electron reduction at inert electrodes.
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