Influence of temperature on thermoelectric properties of FexCo1− xS2 thin films: a semiconductor to semimetal conversion

JM Clamagirand, JR Ares, E Flores, P Diaz-Chao… - Thin Solid Films, 2016 - Elsevier
In this work, we investigate the thermoelectric properties of p and n-type thin films obtained
by cobalt doping of FeS 2. Films were synthesized by direct sulfuration of Co–Fe thin
bilayers at 300° C. It is found that at room temperature (RT), the Seebeck coefficient is
reduced from 80 μV/K to− 70 μV/K when Co concentration is increased and the electrical
resistivity of the films is decreased two orders of magnitude. X-ray diffraction and Raman
measurements point out that Co is replacing Fe into the pyrite lattice and, subsequently is …
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