Infrared Spectra of HCl−H2O Clusters in Helium Nanodroplets

SD Flynn, D Skvortsov, AM Morrison… - The Journal of …, 2010 - ACS Publications
SD Flynn, D Skvortsov, AM Morrison, T Liang, MY Choi, GE Douberly, AF Vilesov
The Journal of Physical Chemistry Letters, 2010ACS Publications
Small (HCl) m (H2O) n clusters have been assembled in He droplets, and their spectra in the
HCl stretch range (2500− 3000 cm− 1) have been obtained. In a recent He droplet study, a
band at 2670 cm− 1 was assigned to the dissociated H3O+ (H2O) 3Cl− ion pair. In this work,
we have revised the assignment of this band to a cyclic hydrogen-bonded form of the (HCl) 2
(H2O) 2 cluster based on careful measurements of the pickup pressure dependence as well
as the transition moment angles associated with the HCl stretch vibrations. A number of …
Small (HCl)m(H2O)n clusters have been assembled in He droplets, and their spectra in the HCl stretch range (2500−3000 cm−1) have been obtained. In a recent He droplet study, a band at 2670 cm−1 was assigned to the dissociated H3O+(H2O)3Cl ion pair. In this work, we have revised the assignment of this band to a cyclic hydrogen-bonded form of the (HCl)2(H2O)2 cluster based on careful measurements of the pickup pressure dependence as well as the transition moment angles associated with the HCl stretch vibrations. A number of vibrational bands due to small mixed clusters have also been observed. As the number of the captured water molecules increases, a broad feature appears that spans the 2550−2800 cm−1 range. The possible origin of this spectral broadening in large (HCl)m(H2O)n clusters is discussed.
ACS Publications
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