Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M 2 (dhtp)(CPO-27-M; M= Ni, Co, Mg)
Chemical Communications, 2010•pubs.rsc.org
Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27
metal–organic framework at low loadings interact significantly more strongly than those
adsorbed successively as a consequence of the strong interaction of hydrogen with the
coordinatively unsaturated metal cations in the framework.
metal–organic framework at low loadings interact significantly more strongly than those
adsorbed successively as a consequence of the strong interaction of hydrogen with the
coordinatively unsaturated metal cations in the framework.
Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal–organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.
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