Laser Stark spectroscopy of the fundamental bands of HNO (ν2 and ν3) and DNO (ν1 and ν2)

JWC Johns, ARW McKellar - The Journal of Chemical Physics, 1977 - pubs.aip.org
The V 2 (NO stretch) fundamental bands of HNO and DNO and the V3 (bending) band of
HNO in the 6.5! Jm region have been studied using the technique of laser Stark
spectroscopy. The experiment utilized a Stark cell located inside the cavity of a CO laser,
with the short-lived HNO molecules produced in a flow system by the reaction H+ NO-; HNO.
Accurate values for the band origins, rotational constants, and dipole moments were
obtained from analyses of 35 transitions in DNO and over 40 in HNO. The Coriolis …
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