Mechanical control of enantioselectivity of amino acid recognition by cholesterol-armed cyclen monolayer at the air-water interface
T Michinobu, S Shinoda, T Nakanishi… - Journal of the …, 2006 - ACS Publications
Journal of the American Chemical Society, 2006•ACS Publications
Monolayers of the cholesterol-armed cyclen Na+ complex at the air− water interface display
a remarkable, surface pressure dependent enantioselectivity of amino acid recognition.
Upon compression of the monolayer, the binding constants of amino acids increase
accompanying an inversion of chiral selectivity from the d-to l-form in the case of valine.
a remarkable, surface pressure dependent enantioselectivity of amino acid recognition.
Upon compression of the monolayer, the binding constants of amino acids increase
accompanying an inversion of chiral selectivity from the d-to l-form in the case of valine.
Monolayers of the cholesterol-armed cyclen Na+ complex at the air−water interface display a remarkable, surface pressure dependent enantioselectivity of amino acid recognition. Upon compression of the monolayer, the binding constants of amino acids increase accompanying an inversion of chiral selectivity from the d- to l-form in the case of valine.
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