Mild and efficient allylation of aldehydes by using copper fluorapatite as catalyst
ML Kantam, GT Venkanna, KBS Kumar… - Advanced Synthesis …, 2008 - Wiley Online Library
ML Kantam, GT Venkanna, KBS Kumar, V Balasubrahmanyam, G Venkateswarlu…
Advanced Synthesis & Catalysis, 2008•Wiley Online LibraryA facile synthesis of homoallylic alcohols is achieved by the allylation of aldehydes with
allylic metal reagents or allyl halides using copper fluorapatite (CuFAP) as catalyst under
mild reaction conditions. A variety of aldehydes were converted to the corresponding
homoallylic alchohols, demonstrating the versatility of the reaction.
allylic metal reagents or allyl halides using copper fluorapatite (CuFAP) as catalyst under
mild reaction conditions. A variety of aldehydes were converted to the corresponding
homoallylic alchohols, demonstrating the versatility of the reaction.
Abstract
A facile synthesis of homoallylic alcohols is achieved by the allylation of aldehydes with allylic metal reagents or allyl halides using copper fluorapatite (CuFAP) as catalyst under mild reaction conditions. A variety of aldehydes were converted to the corresponding homoallylic alchohols, demonstrating the versatility of the reaction.
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