[HTML][HTML] Muon-spin relaxation and AC magnetometry study of the ferrimagnet LaSr2Cr2SbO9

EC Hunter, PD Battle, SJ Blundell, CV Topping… - Journal of Solid State …, 2019 - Elsevier
EC Hunter, PD Battle, SJ Blundell, CV Topping, FKK Kirschner, F Lang
Journal of Solid State Chemistry, 2019Elsevier
AC susceptibility and muon spin relaxation data have been collected from a polycrystalline
sample of LaSr 2 Cr 2 SbO 9, a perovskite-like compound wherein the unequal distribution
of Cr 3+ and Sb 5+ cations over two crystallographically-distinct six-coordinate B sites
results in the onset of ferrimagnetism at~ 150 K. The data are used to elucidate the dynamics
of the ferrimagnetic domain walls, thought to lie in Sb-rich regions, and suggest an energy
barrier of~ 0.13 eV to their motion. The muon data confirm that the ferrimagnetic order is a …
Abstract
AC susceptibility and muon spin relaxation data have been collected from a polycrystalline sample of LaSr2Cr2SbO9, a perovskite-like compound wherein the unequal distribution of Cr3+ and Sb5+ cations over two crystallographically-distinct six-coordinate B sites results in the onset of ferrimagnetism at ~150 K. The data are used to elucidate the dynamics of the ferrimagnetic domain walls, thought to lie in Sb-rich regions, and suggest an energy barrier of ~0.13 eV to their motion. The muon data confirm that the ferrimagnetic order is a true bulk phenomenon. The behaviour of this material is briefly compared to that of Ni2+- based relaxor ferromagnets.
Elsevier
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