Nanoscale spherical architectures fabricated by metal coordination of multiple dipyrrin moieties

H Maeda, M Hasegawa, T Hashimoto… - Journal of the …, 2006 - ACS Publications
H Maeda, M Hasegawa, T Hashimoto, T Kakimoto, S Nishio, T Nakanishi
Journal of the American Chemical Society, 2006ACS Publications
Phenylethynyl-bridged dipyrrin “dimers” have performed ZnII complexation to give
coordination polymers, which provided the fluorescent colloidal spherical objects in solution
as well as on the substrate according to the spacer units. Using a mixture of THF and water,
unique morphologies, such as bell-shaped and “golf ball”-like architectures, were observed.
Phenylethynyl-bridged dipyrrin “dimers” have performed ZnII complexation to give coordination polymers, which provided the fluorescent colloidal spherical objects in solution as well as on the substrate according to the spacer units. Using a mixture of THF and water, unique morphologies, such as bell-shaped and “golf ball”-like architectures, were observed.
ACS Publications
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