New Approaches to Functionalizing Metal‐Coordinated N2
JG Andino, S Mazumder, K Pal, KG Caulton - … Chemie International Edition, 2013 - infona.pl
JG Andino, S Mazumder, K Pal, KG Caulton
Angewandte Chemie International Edition, 2013•infona.plN 2, can do: Converting the refractory molecule N 2 into synthetic chemicals is
thermodynamically preferred when the derivatizing reactant is a “high‐energy molecule”,
one with a positive enthalpy of formation. Alkynes and allenes are thus targeted for this
purpose (see scheme), and a range of likely products are identified, especially those with
N N bonds, including bipyrroles.
thermodynamically preferred when the derivatizing reactant is a “high‐energy molecule”,
one with a positive enthalpy of formation. Alkynes and allenes are thus targeted for this
purpose (see scheme), and a range of likely products are identified, especially those with
N N bonds, including bipyrroles.
N2, can do: Converting the refractory molecule N2 into synthetic chemicals is thermodynamically preferred when the derivatizing reactant is a “high‐energy molecule”, one with a positive enthalpy of formation. Alkynes and allenes are thus targeted for this purpose (see scheme), and a range of likely products are identified, especially those with NN bonds, including bipyrroles.
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