The article reports new data on the occurrence of three species of apothecial ascomycetes of the Pyronemataceae family collected in the Carpathian Biosphere Reserve. Aleurina subvirescens and Smardaea purpurea were found in Ukraine for the first time, Ramsbottomia asperior was previously found by us also at other localities in Ukraine, including the Carpathian Biosphere Reserve, but without any details and illustrations. For each species a description of the Ukrainian specimens, collection data, macro-and micrographs are provided here. In addition to morphological characters, ecological characteristics and data on the general distribution of these species are briefly discussed.